The Rate of the Reaction between and at Interstellar

The reaction between the radical and the stable hydrocarbon is one of the simplest 2 22 neutral-neutral hydrocarbon reactions in chemical models of dense interstellar clouds and carbon-rich circumstellar shells. Although known to be rapid at temperatures o300 K, the reaction has yet to be studied at lower temperatures. We present here ab initio calculations of the potential surface for this reaction and dynamical calculations to determine its rate at low temperature. Despite a small potential barrier in the exit channel, the calculated rate is large, showing that this reaction and, most probably, more complex analogs contribute to the formation of complex organic molecules in low-temperature sources. Subject headings : ISM: abundances È ISM: clouds È ISM: molecules È molecular processes